Physical Chemistry I
In this Curricular Unit, Students will:
- Master basic concepts of quantum mechanics (quantization, Copenhagen interpretation of quantum mechanics).
- Master calculation tools in quantum mechanics (normalization of the wave function, conceptual models in quantum).
- Deepen the understanding and analysis of Electronic Spectroscopy (Atomic and Molecular) and Vibrational Spectroscopy (Infrared and Raman).
- Understand the phenomena of Light Absorption and Emission.
- Know how to relate the structure of molecules and materials with the experimental results of optical spectroscopy.
César Antonio Tonicha Laia, João Carlos dos Santos Silva e Pereira de Lima
Weekly - 4
Total - 80
- Basic knowledge of Calculus.
- Good knowledge of General Chemistry.
- Mastery of Classical Physics.
"Physical Chemistry", Peter Atkins and Julio de Paula, Oxford University Press, 9th edition or later.
- Online theoretical classes via Zoom
- Theoretical-practical classes, with problem solving
- laboratory classes
- The frequency of the subject is obtained by performing all practical assignments with positive information (5) (previous preparation is required) and delivering the reports.
- Pratical Evaluation:
- 70% Reports of the 5 APs,
- 30% Oral Presentation of one AP.
- Theoretical Evaluation:
- Tests (3 tests): minimum 9.5 out of 20 (average value)
Final Grade = 0,67 x Theoretical Grade + 0,33 Laboratory Grade
Origins of Quantum Mechanics
Black Body Radiation and Photoelectric Effect
Schrödinger equation. Born''s interpretation of wave function and normalization.
Heisenberg''s Principle of Uncertainty and Postulates of Quantum Mechanics
Applications of quantum mechanics: particle in a box, tunnel effect, vibrational motion. Quantum numbers.
Hydrogen atom structure.
Electronic transitions and transition rules.
Huckel''s method. Aromaticity.
Electronic states of molecules and spectroscopy.
Fluorescence and Phosphorescence.
Vibrational Spectroscopy (Infrared and Raman).
Symmetry Applications in Vibrational Spectroscopy and Electronics.